Crystalline Silicotitanates--new Ion Exchanger for Selective Removal of Cesium and Strontium from Radwastes

Download or read book Crystalline Silicotitanates--new Ion Exchanger for Selective Removal of Cesium and Strontium from Radwastes written by and published by . This book was released on 1996 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: A new class of inorganic ion exchange material called crystalline silicotitanates (CST) has been developed for radioactive waste treatment in a collaborative effort between Sandia National Laboratories and Texas A & M University. The Sandia National Laboratories Laboratory Directed Research and Development program provided the initial funding for this effort and this report summarizes the rapid progress that was achieved. A wide range of compositions were synthesized, evaluated for cesium (Cs) removal efficiency, and a composition called TAM-5 was developed that exhibits high selectivity and affinity for Cs and strontium (Sr). Tests show it can remove parts per million concentrations of Cs from highly alkaline, high-sodium, simulated radioactive waste solutions modeled after those at Hanford, Oak Ridge, and Savannah River. In experiments with solutions that simulate highly alkaline Hanford defense wastes, the crystalline silicotitanates exhibit distribution coefficients for Cs of greater than 2,000 ml/g, and distribution coefficients greater than 10,000 ml/g for solutions adjusted to a pH between 1 and 10. In addition, the CSTs were found to exhibit distribution coefficients for Sr+ greater than 100,000 ml/g and for plutonium of 2,000 ml/g from simulated Hanford waste. The CST crystal structure was determined and positions of individual atoms identified using x-ray and neutron diffraction. The structural information has permitted identification of the ion exchange sites and provided insights into the strong effect of pH on Cs ion exchange. Information on the synthesis, composition, and structure of CST is considered proprietary and is not discussed in this report.